How to boot Windows 10 from Mac using exFAT 64gb drive

I am a Mac user prior to purchasing my DIY laptop from Framework, so I ran into some difficulty with the Windows 10 installation/boot. I have a 64gb USB drive that I am using for this. I formatted the drive as exFAT and downloaded the ISO package from windows which I then opened to copy the contents onto the drive. I plugged the drive into the USB-A expansion card but I get this message once the laptop has powered on “Default Boot Device Missing or Boot Failed.” I can’t see what the issue is/what I missed in setting up the drive. Any ideas?

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